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Unfilled PPO

Unfilled PPO is a grade of PPO. It has the lowest strength compared to the other variants of PPO. The graph bars on the material properties cards below compare unfilled PPO to: polyphenylene plastics (top), all thermoplastics (middle), and the entire database (bottom). A full bar means this is the highest value in the relevant set. A half-full bar means it's 50% of the highest, and so on.

Mechanical Properties

Elastic (Young's, Tensile) Modulus

2.4 GPa 0.35 x 106 psi

Elongation at Break

28 %

Flexural Modulus

2.5 GPa 0.37 x 106 psi

Flexural Strength

92 MPa 13 x 103 psi

Impact Strength: Notched Izod

270 J/m 5.0 ft-lb/in

Rockwell R Hardness

120

Tensile Strength: Ultimate (UTS)

63 MPa 9.1 x 103 psi

Thermal Properties

Glass Transition Temperature

210 °C 410 °F

Heat Deflection Temperature At 1.82 MPa (264 psi)

120 °C 260 °F

Heat Deflection Temperature At 455 kPa (66 psi)

140 °C 280 °F

Maximum Temperature: Autoignition

420 °C 790 °F

Maximum Temperature: Decomposition

440 °C 820 °F

Maximum Temperature: Mechanical

100 °C 220 °F

Melting Onset (Solidus)

280 °C 530 °F

Specific Heat Capacity

1250 J/kg-K 0.3 BTU/lb-°F

Thermal Conductivity

0.16 W/m-K 0.093 BTU/h-ft-°F

Thermal Expansion

60 µm/m-K

Vicat Softening Temperature

150 °C 310 °F

Electrical Properties

Dielectric Constant (Relative Permittivity) At 1 Hz

2.7

Dielectric Strength (Breakdown Potential)

19 kV/mm 0.74 V/mil

Electrical Dissipation At 1 Hz

0.0010

Electrical Resistivity Order of Magnitude

15 10x Ω-m

Otherwise Unclassified Properties

Density

1.1 g/cm3 67 lb/ft3

Limiting Oxygen Index (LOI)

32 %

Water Absorption After 24 Hours

0.070 %

Common Calculations

Stiffness to Weight: Axial

1.2 points

Stiffness to Weight: Bending

41 points

Strength to Weight: Axial

16 points

Strength to Weight: Bending

33 points

Thermal Diffusivity

0.12 mm2/s

Thermal Shock Resistance

31 points

Followup Questions

Further Reading

SPI Plastics Engineering Handbook of the Society of the Plastics Industry, Inc., 5th ed., Michael L. Berins (editor), 2000

Modern Plastics Handbook, Charles A. Harper (editor), 1999

Plastics Materials, 7th ed., J. A. Brydson, 1999

CRC Materials Science and Engineering Handbook, 4th ed., James F. Shackelford et al. (editors), 2015