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Polyphenylene Oxide (PPO)

PPO is a thermoplastic, further classified as a polyphenylene plastic.

The properties of PPO include three common variations. This page shows summary ranges across all of them. For more specific values, follow the links immediately below. The graph bars on the material properties cards further below compare PPO to: polyphenylene plastics (top), all thermoplastics (middle), and the entire database (bottom). A full bar means this is the highest value in the relevant set. A half-full bar means it's 50% of the highest, and so on.

Mechanical Properties

Elongation at Break

3.5 to 28 %

Flexural Modulus

2.5 to 8.6 GPa 0.37 to 1.2 x 106 psi

Flexural Strength

92 to 140 MPa 13 to 20 x 103 psi

Impact Strength: Notched Izod

80 to 270 J/m 1.5 to 5.0 ft-lb/in

Tensile Strength: Ultimate (UTS)

63 to 140 MPa 9.1 to 20 x 103 psi

Thermal Properties

Heat Deflection Temperature At 1.82 MPa (264 psi)

120 to 140 °C 260 to 280 °F

Maximum Temperature: Mechanical

100 to 110 °C 220 °F

Specific Heat Capacity

1020 to 1250 J/kg-K 0.24 to 0.3 BTU/lb-°F

Thermal Expansion

25 to 60 µm/m-K

Electrical Properties

Dielectric Constant (Relative Permittivity) At 1 Hz

2.7 to 3.2

Dielectric Strength (Breakdown Potential)

19 to 21 kV/mm 0.74 to 0.82 V/mil

Electrical Dissipation At 1 Hz

0.0010 to 0.0020

Electrical Resistivity Order of Magnitude

15 10x Ω-m

Otherwise Unclassified Properties

Density

1.1 to 1.4 g/cm3 67 to 87 lb/ft3

Limiting Oxygen Index (LOI)

32 %

Water Absorption After 24 Hours

0.060 to 0.070 %

Common Calculations

Strength to Weight: Axial

16 to 27 points

Strength to Weight: Bending

33 to 42 points

Followup Questions

Further Reading

Reinforced Plastics Durability, Geoffrey Pritchard (editor), 1999

SPI Plastics Engineering Handbook of the Society of the Plastics Industry, Inc., 5th ed., Michael L. Berins (editor), 2000

Modern Plastics Handbook, Charles A. Harper (editor), 1999

Plastics Materials, 7th ed., J. A. Brydson, 1999

CRC Materials Science and Engineering Handbook, 4th ed., James F. Shackelford et al. (editors), 2015